|
|Section2= |Section7=〔http://cameochemicals.noaa.gov/chemical/4808〕 }} Zinc cyanide is the inorganic compound with the formula Zn(CN)2. It is a white solid that is used mainly for electroplating zinc but also has more specialized applications for the synthesis of organic compounds. ==Physical properties== The structure features the zinc in the familiar tetrahedral coordination environment, all linked by bridging cyanide ligands. The structure consists of two "interpenetrating" structures. Such motifs are sometimes called "expanded diamondoid" structures because the interconnecting atoms are tetrahedral but instead of being directly linked as in diamond, the atoms are separated by additional bonds. Some forms of SiO2 adopt a similar structure, wherein the tetrahedral Si centres are linked by oxides. The cyanide group shows head to tail disorder with any zinc atom having between one and four carbon neighbours, and the remaining being nitrogen atoms. It shows one of the largest negative coefficients of thermal expansion (exceeding the previous record holder, zirconium tungstate). 抄文引用元・出典: フリー百科事典『 ウィキペディア（Wikipedia）』 ■ウィキペディアで「Zinc cyanide」の詳細全文を読む スポンサード リンク
|